Electrochemistry
Online ISSN : 2186-2451
Print ISSN : 1344-3542
ISSN-L : 1344-3542
73 巻, 10 号
選択された号の論文の13件中1~13を表示しています
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Headline
  • Yun-S. LEE, Sung-J. CHO, Yang-K. SUN, Koichi KOBAYAKAWA, Yuichi SATO
    2005 年 73 巻 10 号 p. 874-882
    発行日: 2005/10/05
    公開日: 2019/06/01
    ジャーナル フリー

    Two lithium iron oxides have been synthesized at low temperatures by the conventional solid-state method. Orthorhombic LiFeO2 has been synthesized using LiOH and γ-FeOOH at 150°C was composed of orthorhombic LiFeO2 and small amount of spinel LiFe5O8 phases. A Li/LiFeO2 cell showed not only a fairly high initial discharge capacity of over 150 mAh g−1 but also a good cycle retention rate at room temperature. It was found that the orthorhombic phase of the LiFeO2 underwent a structural change to the LiFe5O8 spinel phase in the first cycle. Especially, it showed a severe structural change during the first discharge process, which might be the main reason for the capacity loss of the Li/LiFeO2 system. An amorphous-like LixFeyOz has been synthesized using LiOH and α-FeOOH at 200°C consisted of three kinds of structures, LiFe5O8, Li5FeO4, and a trace of cubic α-LiFeO2 A Li/LixFeyOz cell showed a very high initial discharge capacity (215 mAh g−l) as well as an excellent cycle retention rate (95%) from the 11th to the 50th cycle. It was found that LixFeyOz material was transformed into the spinel LiFe5O8 and tetragonal β-LiFeO2 phases after long-term cycling.

報文
技術報文
  • 原 浩二郎, 猪狩 真一, 高野 真悟, 藤橋 岳
    2005 年 73 巻 10 号 p. 887-896
    発行日: 2005/10/05
    公開日: 2019/06/01
    ジャーナル フリー

    Photovoltaic performance of dye-sensitized solar cells (DSSCs) based on a nanocrystalline TiO2 electrode have been measured in terms of I-V characteristics under standard AM 1.5 G irradiation and spectral response (incident photon to current conversion efficiency, IPCE) of the cells. The performance of DSSCs depended remarkably on the measurement conditions. It has been observed that the conventional characterization conditions for photovoltaic performance of crystalline and amorphus silicon solar cells are not suitable for characterization of DSSCs. In this paper, we suggest suitable characterization conditions, which are to be standard measurement conditions in the near future, for the photovoltaic performance of DSSCs.

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特集
界面ナノ構造・機能解析の最先端
電気化学:測定と解析のてびき
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