Electrochemistry
Online ISSN : 2186-2451
Print ISSN : 1344-3542
Volume 82 , Issue 4
Showing 1-14 articles out of 14 articles from the selected issue
Preface
Articles
  • Shigeo HAYASHI
    2014 Volume 82 Issue 4 Pages 258-263
    Published: April 05, 2014
    Released: April 05, 2014
    JOURNALS OPEN ACCESS
    One-dimensional electrochemical cellular automaton (1D-ECA) has been extended so that effects of axial uniform flows toward the electrode can be simulated. The model is characterized by a sink connected to the terminating cell and a pair of asymmetric propagation probabilities that enables a drift with a constant velocity toward the electrode. The plots of the reciprocal stationary-state current and the reciprocal flow velocity yield a line, whose intercept corresponds to the current in the limit of fast mass transport.
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  • Gyoung-Ja LEE, Sang-Kyu LEE, Ju-Myoung KIM, Chang Kyu RHEE, Yang-Kyu L ...
    2014 Volume 82 Issue 4 Pages 264-266
    Published: April 05, 2014
    Released: April 05, 2014
    JOURNALS OPEN ACCESS
    Potentiometry utilizing redox reactions in a [Fe(CN)6]3−/[Fe(CN)6]4− redox-reagent solution has been considered as simple, highly sensitive, fast, and inexpensive method for evaluating total antioxidant activity (TAA) in various samples such as drinks, food, blood, etc. In this study, for the first time, the determination of TAA using potentiometric method has been applied to depression rating. For a depressed group of 94 persons and a normal group of 66 persons, beck depression inventory (BDI) score and TAA value were evaluated. From a comparison of BDI and TAA results, it is found that the TAA value is closely related to the BDI score and the value of TAA increases with decreasing BDI score. The plot of TAA vs. BDI exhibited a linear relationship with a negative correlation (Pearson’s coefficient r = −0.318, P < 0.01). This strongly suggests that the potentiometric method for TAA determination has a potential to be used as a clinical tool in depression.
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  • Il Chan JANG, Shintaro IDA, Tatsumi ISHIHARA
    2014 Volume 82 Issue 4 Pages 267-272
    Published: April 05, 2014
    Released: April 05, 2014
    JOURNALS OPEN ACCESS
    The effects of Li utilization on the capacity and cycle stability of Li-O2 batteries were studied by investigating the performance of cells incorporating varying ratio of Li metal to air electrode catalyst. The quantity of Li metal was found to affect the overall discharge capacity, such that the capacity decreased with decreasing amounts of Li in the anode. Although a capacity of only 354 mAh g−1 (cathode) was obtained when the anode contained 0.9 mg Li, almost 100% of the Li in the cell was consumed during discharge, which corresponds to a capacity of 3932 mAh g−1 (Li). The cycle stability of cells operating under high Li utilization conditions was, however, significantly reduced. Detailed analysis of the Li distribution in the cell suggests that decreased usage of Li within the first few cycles is the cause of the poor cycle stability. The results of this study suggest that low cycle stability in a Li-O2 battery may be attributed to the formation of a surface passivation layer on the Li metal composed primarily of Li2CO3 and ROCO2Li and generated by reaction with the electrolyte.
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