Fullerene, C
60, is readily reduced to its anion radical, C
60•−, in nitrobenzene (NB) that contains a tetraphenylborate ion (TPB
−) under irradiation with visible light. Fullerene excited by visible light withdraws one electron from TPB
− to form C
60•− and generated TPB radical decomposes. C
60•− can be stored for several days without any changes in deaerated NB. However, as soon as the NB solution containing C
60•− is bubbled with air, C
60•− immediately oxidizes to C
60. Using this photochemical reaction of C
60, we have developed a new-type of photovoltaic cell that can generate and store electricity. We call this cell a photoelectrochemical condenser (PEC). The anodic reaction of the PEC is the oxidation of C
60•− to C
60; although many reduction reactions are possible, the cathodic reaction is chosen to be the reduction of Fe
3+ to Fe
2+ in an aqueous phase. When the PEC was irradiated with visible light ranging from 400 nm to 700 nm (23.4 mW cm
−2), the electromotive force was measured to be approximately 1100 mV, and an electric current of approximately 2 mA was observed. In this paper, we present the PEC and discuss its performance for generating and storing electricity.
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