Significant amounts of MgO, and excess SiO
2 and Al
2O
3 in anorthites from the island of Miyakejima are estimated by EPMA and X-ray diffraction analysis. The role in the crystal structure establishes Mg, Si and Al cations as CaMgSi
3O
8, ?? Si
4O
8 and AlAl
3SiO
8 endmembers for the anorthite solid solution. Syntheses under dry conditions of anorthites along the joins CaAl
2Si
2O
8- ?? Si
4O
8 and CaAl
2Si
2O
8-CaMgSi
3O
8 conduced to ascertaining the partial solubility limits of these endmembers in the solid solutions, compared with the anomalous anorthites from Miyakejima. The maximum limit of partial solubility of CaMgSi
3O
8 is about 25 mol% to CaAl
2Si
2O
8, and that of ?? Si
4O
8 is nearly 8 mol%. Nevertheless inhomogeneous distribution of Mg cation within this single crystal has an implication for the unstable behavior of Mg cation in the anorthite structure. Chemical shift of MgKαI in the synthetic anorthites affords infallible discrimination of solubility of CaMgSi
3O
8 endmember rather than MgAl
2Si
2O
8.
Condensation of natural occurrences and syntheses of plagioclases with small amounts of CaMgSi
3O
8 and ?? Si
4O
8 components purifies that anorthites from Miyakejima may have been originally crystallized by super-cooling in SiO
2-saturated and Mg-rich host magma at the hightemperature more than 1, 000°C, and that the phenomenon in anorthite similar to Tschermak substitution, Mg+Si⇔2Al, goes to prove the charge-coupled substitution of Mg+Si in only tetrahedral sites. Emphasis is placed upon experimental verification and comparison to observed data is made where possible.
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