Investigations concerning the concentration of minor elements (Co, Ni, Mn, As) in pyrites and cube-edge measurements were carried out on thirty-nine specimens taken from the Chichibu mine (26 samples), the Taishu mine (7 samples), and the Ashio mine (6 samples), by using X-ray fluorescent method as well as X-ray diffraction method. The results obtained are as follows;
(1) Pyrites in the Chichibu mine and the Taishu mine show considerably higher in Co and Ni contents, and also in the Co: Ni ratio than in the Ashio mine. As to the contents of both Mn and As in pyrites, the results show only slight differences among three mines.
(2) Generally speaking, the Co and Ni contents and the Co: Niratios in pyrites correlate negatively with the As contents, but correlate positively with Co and Mn contents.
(3) While As contents of pyrites decreases with depth at the mines, the Co content and the Co: Ni ratio increase; no significant trends with depth arc observed in Ni and Mn contents.
(4) The result of the present study indicates that pyrites from high-temperature deposits show generally high Co content and high Co: Ni ratio, and inversely low As content.
(5) The cube-edges of pyrites measured range from 5.4175
9 to 5.4193
7 A. It seems probable that the values increase with the increase of the amounts of both Co and As components in pyrites. The equation pertaining to the cubeedge of pyrite can be written as
Z=5.41752+0.0634X+0.0025Y,
where Z(A) is an unit cell size, X and Y are weight percentages of Co and As components, respectively.
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