An unusual magnesium carbonate hydrate mineral, Mg
5 (CO
3)
4 (OH)
2•8H
2O, was found as encrustments of snow-white oolitic, botryoidal and reniform aggregates on the weathered surface of the brucite-bearing serpentinites from Yoshikawa, Aichi Prefecture, Japan. The empirical formula is similar to that of hydromagnesite except its having more H
2O contents. Individual grains of the mineral are flaky and slightly soluble in distilled water.
This mineral has a long spacing of 33.2Å, which decreases gradually with rising temperature and completely disappears on heating up to 150°C. The long spacing does not expand with ethylene glycol. X-ray diffraction and infrared spectrum patterns for the 150°C-heated sample are similar to those for hydromagnesite.
DTA curve for this mineral shows five endothermic reactions with maxima at 40, 114, 270, 410, and 515°C, and an exothermic reaction at 496°C. The first two endotherms are considered to be caused by removal of interlayer water yielding the superlattice structure.
The optical properties are as follows: α=1.515, β=1.521, γ=1.522, and 2V (-)=44.5° (calculated).
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