Subsurface gases have been surveyed in the fault zones around the Median Tectonic Line in western Shikoku Island. Thirty-two bubble gas samples have been collected for this purpose, and their chemical compositions have been determined gas chromatographically. The He/Ar, Ne/Ar, N
2/Ar and CH
4/Ar ratios of the bubble gas samples suggest that substantial separation of He from Ne has been revealed to interfere seriously with the He/Ar determination using carrier gas of oxygen when the He/Ne ratio of sample gas is as low as in the atmospheric air. Some experimental conditions to reduce the interference have been proposed. The He/Ar, Ne/Ar, N
2/Ar and CH
4/Ar ratios of the bubble gas samples suggest that substantial amounts of He and CH
4 produced in subsurface rocks are added to groundwaters and that almost all Ne, Ar and N
2 of subsurface gases are of the atmospheric origin. Concentrations of major and minor gas components of the bubble gases are considerably variable reflecting the types of subsurface rocks. CO
2-rich bubble gases with relatively high CH
4/Ar ratios are commonly observed in the Sambagawa schist zone, and their He/Ar and CH
4/Ar ratios are highly fluctuating according to unsteady discharges of CO
2-rich gases containing He and CH
4 from underground. N
2-rich bubble gases with relatively low CH
4/Ar ratios are predominant in the Ryoke granite zone. Some of their He/Ar ratios are fifty to ninety times as high as the atmospheric ratio. The intimate relationship between the bubble gas compositions and the types of subsurface rocks may encourage seismo-geochemical studies of subsurface gases and may suggest that CH
4/Ar as well as He/Ar is a possible seismo-geochemical parameter in this region.
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