The hydrogen isotopic composition of hornblendes (Hb) and biotites (Bi) from Quaternary volcanic rocks along the Kamchatka-Kurile volcanic arcs was measured. Volcanoes from three different tectonic environments were sampled: The Kurile chain, East Kamchatkan volcanic belt and Sredinny Ridge. Large local and regional variations were observed. There is no correlation between δ
D values of minerals and their chemical composition, including Cl and F contents. All observed trends are caused by regional variations in the major element chemistry (Hb) or Cl and F contents (Bi). Minerals from the Kuriles and East Kamchatka are most enriched in D, have a low F content, and a high Cl content, the latter 500-1000 ppm. Hb and Bi from Sredinny Ridge are D-depleted, enriched in F (up to 1.7 wt.% in Bi) and depleted in Cl. Based on the data set for Shiveluch and Avacha volcanoes, δ
D variations for Hb are caused mainly by degassing of the erupted material; the most degassed rocks contained the most D-depleted Hb. We believe that the maximum δ
D values correspond to isotopic equilibrium of OH-bearing minerals with a “parent magmatic water”, dissolved in the melt prior to eruption. Magmatic water for the Kurile volcanoes with δ
D in the range of -40 to -25‰ could be derived mainly from subducted oceanic sediments. Magmatic water for the East Kamchatka volcanoes is slightly depleted in D (-46 to -36%) and corresponds to a mixture of “devolved” water from subducted sediments and water released from altered basalts of oceanic crust. The water source of the Sredinny Ridge magmas with δ
D values in the range of -70 to -80‰ may not be related to oceanic slab-derived fluids; rather, they may preserve a depleted mantle isotopic signature. The regional variation of maximum D/H ratios for Hb and Bi agrees well with trends of the Sr isotopic composition and the
10Be content in volcanic rocks throughout the modem Kurile-Kamchatka arc.
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