Experiments on the simultaneous partitioning of divalent metal ions were performed in the systems (1) ZnS (sphalerite)−(Ni
2+, Co
2+, Fe
2+, Mn
2+, Cd
2+)Cl
2−H
2O and (2) Mn
3Al
2Si
3O
12 (spessartine)−(Ni
2+, Mg
2+, Co
2+, Zn
2+, Fe
2+, Ca
2+)Cl
2−H
2O in the temperature range of 500 to 800°C at 1 kb. In the former system for ion partitioning in the 4-fold coordination, parabola-shaped PC-IR curves with a peak near Zn
2+ were obtained and no anomaly was observed for Zn
2+ and Ni
2+ but Cd
2+. In the latter system for ion partitioning in the 8-fold coordination, parabola-shaped PC-IR curves with a peak near Mn
2+ were obtained, but Zn
2+ deviates from such a trend and tends to concentrate into aqueous chloride solutions. The PC-IR curves for spessartine are gentle compared with those for sphalerite. The PC-IR curves both for spessartine and sphalerite become gentle with increasing temperature.
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