The slab-derived fluids and/or hydrous slab melts released from a subducted slab ascend into the mantle wedge, lower its melting temperature and thus induce generation of hydrous arc magmas. The estimation of H
2O concentration in primary arc magmas provides an important constraint on pressure and temperature conditions of magma generation at subduction zones. This paper gives an overview of the estimation of H
2O concentration in primary arc magmas by combining two petrological methods: experimental petrological studies and analyses of melt inclusions. Melting experiments of hydrous primary arc magmas have clarified that the
P-T condition of magma generation shifts toward lower temperature and higher pressure with increasing H
2O concentration. Another experimental constraint is that only primary magmas with low H
2O (≤ 2 wt%) can erupt without modification of their primary composition by crystallization differentiation due to comparable
dT/dP between olivine liquidus and basalt adiabat. However, this does not exclude presence of hidden H
2O-rich primary magmas at depths. Indeed, the H
2O concentrations in primary melt estimated from the analyses of primitive melt inclusions suggest wide variation (e.g., ~ 2 wt% at Kamchatka arc and ~ 4 wt% at Central American arc). H
2O-rich primary magmas may ascend and erupt after differentiation and/or supply volatiles to magmas at shallower level and cause so-called “excess degassing”. Analyses of melt inclusions also clarified that the H
2O concentration in primitive melt inclusions is almost constant or decrease from volcanic front to rear arc. This observation is opposite to a previous understanding that H
2O concentration in primary melt increases as well as incompatible K
2O across the arc.
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