NIPPON GOMU KYOKAISHI
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Volume 83, Issue 2
Displaying 1-3 of 3 articles from this issue
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Advanced Course on Rubber Science and Technology
  • Living Radical Polymerization 4.  Stereospecific Living Radical Polymerization
    Shigeru YAMAGO, Yasuyuki NAKAMURA
    2010 Volume 83 Issue 2 Pages 35-39
    Published: 2010
    Released on J-STAGE: August 25, 2010
    DOIhttps://doi.org/10.2324/gomu.83.35
    JOURNAL FREE ACCESS
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    Living radical polymerization (LRP) enables the control of molecular weight and molecular weight distribution of polymers synthesized, but it is no effect on stereoregulation (tacticity) of the polymer. With the progress of stereospecific radical polymerizations, several attempts have been made to combine it with LRP to achieve simultaneous control of molecular weight, molecular weight distribution, and tacticity. This forth article describes these stereospecific LRPs. Synthetic routes to stereoblock polymers and stereogradient polymers are also described.
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Introduction to Rubber Science and Technology : Fundamental Physics of Rubber
Technical Note
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