Piezoelectric and ferroelectric properties of bismuth sodium titanate, (Bi
1/2Na
1/2)TiO
3(BNT)-based solid solution, that is, (Bi
1/2Na
1/2)
(1-x)(Pb
aBa
b)
xTiO
3(
a+
b=1)_??_BNPB(100
x-100
a/100
b)_??_, are studied on their piezoelectric properties from the viewpoint of a new group of lead-free or low-lead-content piezoelectric ceramics with a rhombohedral(
Fα)-tetragonal(
Fβ)morphotropic phase boundary(MPB). It is evident that the MPB seems to be remarkably efficacious in promoting piezoelectric and pyroelectric activities by electrical poling.
X-ray diffraction data, dielectric properties and
D-
E hysteresis loops show that the MPB exist near (Bi
1/2Na
1/2)TiO
3_??_BNT_??_at
x=0.13_??_0.14, 0.08_??_0.09 and 0.06_??_0.07 in the case of
b=0,
b=0.5 and
b=1, respectively. BNPB ceramics are superior for piezoelectric ceramics in high frequency ultrasonic uses, or special piezoelectric actuator materials with a lower free permittivity, ε
T33/ε
0, and a high electromechanical coupling factor,
k33, along with a high mechanical strength.
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