The effect of electrical degradation characteristics and microstructure of Sb
2O
3-added-ZnO varistors were investigated by FE-SEM, energy dispersion X-ray spectroscopy (EDX), optical microscope, X-ray diffraction (XRD), and voltage-current (
V-I) characteristics. The nonlinearity index α of
V-I characteristic for the Bi-Mn-Co-Sb
2O
3-added ZnO varistors decreased with increasing amount of Sb
2O
3 after the electrical degradation. The twin crystal of ZnO was formed by the addition of Sb
2O
3. The number of twin crystal, of which two
c-axes are perpendicular to twin plane, increased and the number of twin crystal, of which two
c-axes are parallel to twin plane, decreased with increasing the amount of addition of Sb
2O
3. It is suggested that electrical degradation is affected by combination of orientation of ZnO grains containing twin planes and double Schottky barrier may be not formed in the twin plane.
抄録全体を表示