The RF (13.56 MHz) gas breakdown in Ne-N
2, Ne-Ar and He-N
2 mixture systems are investigated experimentally in a parallel plate capacitively coupled device with varying the pressure, the mixing ratio and the electrode separation, specifically focussing on the breakdown at the small values of the mixing ratio. The breakdown voltage curves obtained have the V-shaped or L-shaped characteristics. The breakdown voltage decreases with the addition of a small amount of N
2 or Ar in each mixture system, and the ratios of decrease in breakdown voltage to rare gas breakdown voltage in these mixture sysytems are about 22, 32 and 30 % at the maximum, respectively. The decrease of breakdown voltage is observed in a certain restricted pressure range, which is narrower in Ne-N
2 system than in Ne-Ar one. This feature in Ne-N
2 system is probably due to the decrease of electron energy attributed to the vibrational excitation of N
2 by electron impact. Compared with the DC breakdown and the microwave one, the decrease ratio in the RF breakdown is relatively small, suggesting that there exist some competitive ionization processes accompanied by excited particles including the Penning ionization.
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