Since the gas discharge plasma easily converts NO to NO
2, which can be reduced more actively in selective catalytic reduction with hydrocarbons (HC-SCR), the plasma-assisted HC-SCR is an effective method for NOx reduction from diesel engine exhaust gases. In this work, the relation between NOx removal and reaction products is investigated in plasma-assisted HC-SCR in simulated flue gas as parameters of gas composition, plasma specific energy and catalyst temperature. C
2H
4 is used as a hydrocarbon and commercially available Al
2O
3 is used as a catalyst. After the plasma treatment of simulated flue gas, HCHO and HCOOH were generated as by-products, while NO was effectively converted to NO
2. These by-products were confirmed to be reactive at lower catalyst temperature than C
2H
4 in HC-SCR. The relation between NOx removal and reaction products suggests that HCHO and HCOOH contribute the effective NOx reduction at low catalyst temperature in plasma-assisted HC-SCR.
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