The variations in the partial pressures of gaseous molecules produced by the decomposition of C
6H
6 in a low pressure DC glow discharge in N
2/C
6H
6 and Ar/C
6H
6 mixtures are measured by the mass spectrometry. Also, rate equations for the partial pressure variations, which consider possible reaction among the gaseous molecules in the low pressure DC glow discharge, with the electrical energy-input, are proposed, and rate constants are determined by fitting the calculated partial pressure variations to the measured partial pressure variations. The rate constants deduced here indicate that C
6H
6 is mainly decomposed into an intermediate, which is regarded as a fragment of C
6H
6, the intermediate is decomposed into mainly C
2H
2, and then C
2H
2 is converted into H
2 and HCN (only in N
2/C
6H
6).
View full abstract