This paper presents experimental studies on cell voltage-current density characteristics and the CO
2 evolution phenomena of phosphoric acid fuel cells for various supplied air/hydrogen, hydrogen/hydrogen, nitrogen/nitrogen, air/air, nitrogen/hydrogen, air/nitrogen and hydrogen/air conditions to the air electrode/fuel electrode, respectively.
No CO
2 gas is detected from a hydrogen-supplied electrode at positive and negaive current conditions. From a nitrogen-supplied electrode operating as an anode, current dependent CO
2 evolution is observed, although no CO
2 is detected from the same electrode operating as a cathode.
There is also CO
2 evolution from an air-supplied electrode near the zero current. The CO
2 evolution can be suppressed slightly by hydrogen diffusion from the opposing electrode.
Cell voltage-current density characteristics are represented as equivalent circuits in which corrosive or non-corrosive current can be evaluated separately. For a hydrogen/hydrogen condition, the cell can be expressed as a resistor having low resistivity. For an air/hydrogen or an air/air condition, the cell can be expressed as a series circuit of ideal cells and resistors, whereas for nitrogen/nitrogen, nitrogen/hydrogen or air/nitrogen conditions diodes should be added to the circuit in order to express the potential barrier. Currents on this potential barrier are zero except for the nitrogen/hydrogen condition where hydrogen is diffused from the opposing electrode.
These characteristics are useful for analyzing performance distribution in cells at transient conditions such as start-up, shut-down or abnormal conditions such as a local circuit in a cell, gas cross over nr over enrrent.
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