Due to the relatively high performance and the compactness, the pulsed-discharge deNO
x process is expected to be one of the next generation technologies to suppress air pollution. However, sufficient guide lines for the optimum operation of pulsed-discharge deNO
x process has not been presented. In this study, we have simulated numerically the process applied by several hundreds pulsed-voltages, and investigated the effects of by-products and ammonia injuction on the deNO
x performance. In a case for the no ammonia injection, both of the N
xO
y removal efficiency and the electric energy consumption to remove N
xO
y change with increasing repetitive pulse number, because electrons produced by the discharge recombine with accumulated by-products, such as of H
3O + (H
2O)
2, followed by decreasing radical concentration and oxidative/reductive removal reactions. In a case for ammonia injection, the removal efficiency increases and the electricity consumption decreases with increasing the ammonia concentration, because removal reactions such as NO →
O NO
2 →
OH HNO
3 →
NH3 NH
4NO
3 and NO →
NH2 N
2 become active. When ammonia is injected excessively, the deNO
x performance declines because the NH
2 radical produced by the electron collision with ammonia reacts with NO
2 to make relatively stable N
2O.
View full abstract