According to the previous studies made by the authors, it has been ascertained that the contents of SiO
2, as an inclusion, increased when the molten cast iron was oxidized and that its increment was remarkably great when the melt was oxidized at the temperature below 1400°C. And also, it was known qualitatively that the possibility of the occurrence of shrinkage cavities became greater as the SiO
2 content increased. The authors have affirmed quantitatively that in many cases the melting conditions in which the melt was oxidized, coincided with the conditions, that lead to occur shrinkage cavities, and examining the phenomena of structural abnormality due to suspending silica, further investigations are carried out so as to study the causes of the formation of shrinkage cavities in the oxidizing melting. The results obtained by this experiment are as follows : (1) In the low temperature oxidizing melting which leads increment of suspending silica, the possibility of the occurrence of shrinkage cavities becomes greater, but contrary to this, in the case of high temperature oxdizing melting in which the suspending silica does not introduce the possibility, it is lessen and this results in sound castings. (2) Shrinkage cavities occur with few exceptions in case of the low temperature and almost non-oxidizing melting, and any connections can be seen between the possibility of the occurrence of shrinkage cavities and suspending silica. However, sound castings can be produced even in the non-oxidizing condition if the melting temperature increased. (3) The shrinkage cavities appeared in the oxidizing melting differ its shape in accordance with the degree of oxidation and, in the intense oxidizing condition, the internal shrinkage becomes smaller and smaller till it turns into external shrinkage. However, the total volume of internal and external shrinkages increase as the rate of oxidation intensified. (4) The causes of the formation of internal shrinkage will have some relations to the structural abnormality which is led by suspending silica in the melt : the precipitation temperature of primary crystal increases and the eutectic temperature is super-cooled, then the zone of solidification becomes wide, consequently the feeding of metals through dendritic primary crystal into the center of the crystal is interrupted. (5) The causes of the formation of external shrinkage are thought that the suspending silica segregates in the center part of the casting and this segregation hasten the completion of solidification and thus the suction of shells into the inner parts becomes great.
抄録全体を表示