There were many investgations on magnesium-treated cast irons, but the arguments were in their solidification processes. In the present paper, the investgations were carried out on the solidification processes of the magnesium-treated Fe-C and Fe-C-Si alloys with different degrees of carbon saturation were discussed. Cast irons having carbon saturation degrees of 0.47∼1.12 were made from the electrolytic iron, the electrode graphite and ferrosilicon containing 75% of Si. Magnesium alloys added were Ni-Cu-Mg, Fe-Si-Mg and Cu-Mg alloys composed from pure metals. 40 grs. of each iron was melted in a Tammann tube in a silit furnace and was treated with magnesium alloy and furnace-cooled while the cooling curve was plotting. At any point of the cooling curve, the specimen was quenched into water and the microstructure was observed. The specimen quenched at each step of cooling showed the structure developed to the time which would show the process of the solidification.
From the experiments mentioned above, the following evidences were observed.
1) There are four types on the formation of nodular graphite in magnesium-treated cast iron ;
I. The separation from the melt as primary graphite.
II. The separation from the melt on the dendrites of the primary austeinite and is enclosed in the followed austenite.
III. The separation from the spheroidal austenite which is supersaturated with carbon.
IV. The separation from the supercooled primary austenite dendrite.
2) The I-process takes place in hyper-eutectic cast iron at the pro-eutectic temperature, the II-process in the hyper-eutectic and slightly hypo-eutectic cast iron below the eutectic temperature, the III-process in slightly hypo-eutectic cast iron under the eutectic temperature after the II-prccess, and the IV-process in the hypo-eutectic cast iron with low degrees of carbon saturation at the end of the solidification process.
3) Inoculation of silicon promotes the I and II-processes, accordingly the increase of nodular numbers by inoculation is more remarkable in the iron with higher carbon saturation degree. For slightly hypo-eutectic cast iron, the inoculation of silicon promotes the II-process and reduces III-process, and the rapid cooling promotes the III-process and reduces the II-process on the contrary.
4) The III-process may be replaced with the ledeburite formation when the silicon content is low, and with the formation of quasiflake graphite when magnesium is added insufficiently. Conequently, the spherodization degree of graphite may be lowest in the slightly hypo-eutectic cast iron, and the degree may be improved by inoculation of silicon.
5) The process of ferrite and pearlite formation in the magnesium-treated cast iron is not so different as that of the flake graphite one, but the austenite around quasi-flake graphite is easier to form ferrite than that around nodular graphite, and for normal flake graphite cast iron, ferrite is hardest to be formed.
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