In the preliminary works, the influences of various treatments of cast iron melt containing Mo and Ni on casting structure were investigated. It was comfirmed that inoculation and Mg-treatment showed a tendency to promote the formation of pearlite and to decrease the amount of bainite matrix in the Mo-Ni cast iron studied. In higher alloy irons, vacuum melting or an addition of Fe
3O
4 caused easily to form acicular matrix with a fine eutectic form of graphite, and Mg-treatment and inoculation with calciumsilicide both formed martensitic matrix of high hardness.
In the present paper, to analyze the above experimental results, the effect of graphite structure on the S-curve (T.T.T diagram) for 0.5%Mo-1.4%Ni cast iron were investigation by microscopic examination in pearlite transformation range and by dilat-metric measurement in bainite range. The results abtained were as follows;
1) The S-curve of Mo-Ni cast iron was divided into two C-curves; the pearlite formation occurs in a temperature range of about 720∼520°C and the bainite formation, about 520∼200°C.
2) In the temperature range of upper pearlite, graphitization occured through both direct and indirect reaction. The letter reaction was accelerated by the presence of fine graphite in cast iron.
3) The beginning and ending points of the upper pearlite trnsformation, which was started at austenite boundary, were almost unaffected by the graphite structure.
4) In the case of cast iron with coarse flaky graphite, the time required for the beginning of lower pearlite reaction was remarkably shortened, and also this reaction was started around the graphite, forming troostitic structure.
5) The distribution of fine graphite moved the S-curve of the beginning and ending for bainite formation to the left, and also produced large amounts of bainite, as interpreted from the dilation curve. The microstructure of bainite was not affected by the graphite structure, but depended upon the reaction temperature. At the relatively higher temperature, the isothermal bainite reaction remained incomplete, with large amounts of austenite untransformed.
6) After austenizing at a high temperature, the isothermal pearlite reaction was accelerated, but the bainite reaction restrained.
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