Despite the many investigations on the effects of various elements on the formation of spheroidal graphite in cast iron there are only a few studies that report on how these elements harmfuly influence the formation of spheroidal graphite. In order to clarify this problem, experiments were conducted to study the inhibitory effects of tellurium and selenium on the formation of spheroidal graphite.
The base metal composed of electrolytic iron and electrode graphite was melted in a high frequency induction furnace and cast into an iron mold. In a fused silica crucible 50 grams of this alloy with a carbon content of 4.35% was placed and melted in a resistance furnace, and then tellurium and selenium up to 1.0% were added to the melt. At 1,350°C the melt was treated with Fe-Si-Mg(21.4%) alloy and cooled while the cooling curve was plotted. On these furnace-cooled specimens, the graphite structure was observed and the spheroidization degree of graphite was measured. Also, X-ray diffraction analysis was carried out on the powder which was produced by the magnesium-treatment in a fused silica crucible.
By increasing the addition of tellurium or selenium, residual magnesium content decreased and the shape of graphite changed successively from spheroidal to vermicular, undercooled and flaky. MgO, MgS and MgSe were determined in the reaction product of the magnesium-treated iron melt containing O, S and Se, respectively. However, MgTe could not determined in the Tecontaining iron because of lack of standard diffraction data. Tellurium and selenium consumed the residual magnesium which was necessary to form the spheroidal graphite just as the inhibitory manner of sulfur and oxygen. According to the previously reported classification of the inhibitory behaviour of the elements in the spheroidization of graphite, i.e. the classification into sulfur type, titanium type and lead type, these two elements were classified into the sulfur type (Mg-consuming type).
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