Radiation damage to 30 vol.% TBP (Tributyl phosphate)/Kerosene solvent was investigated on the behavior changes of fission products and nitric acid in extraction and in stripping with 0.01 N nitric acid at 25°C.
In these extraction-stripping experiments, three types of solvent were used; namely,
60Co γ-ray irradiated (10
4-10
8r) solvent, non-irradiated solvent and synthetic “damaged solvent”, or DBP (Dibutyl phosphate)-MBP (Monobutyl phosphate), Butanol or Pyrophosphoric acid added TBP/Kerosene.
It has been revealed in beaker scale experiments that
95Zr-
95Nb is extremely effected in extraction-stripping with radiation damaged and synthetic damaged solvent comparing with
106Ru-
106Rh,
131l,
144Ce_
144Pr and gross fission products, and that its behavior change depends mainly on the formation of DBP-MBP, but not on that of Butanol or Pyrophosphate.
106Ru-
106Rh is hardly effected in extraction with damaged solvent and is effected only in stripping from damaged solvent.
Neither
144Ce-
144Pr nor nitric acid is influenced by radiation damage to the solvent.
131l behavior change is different from others.
Emulsion formation was observed only in
95Zr-
95Nb extraction with 10
7r or more irradiated and DBP-MBP added solvent (0.1g or more/l-solvent).
Settling time or phase separation time changes may not affect the process significantly except in the case of emulsion formation.
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