(1) Good linear relations were obtained between
P and
m, and the slopes were easily determined. This means that Eq. (3) is held satisfactorily under the conditions used in this experiment.
(2)
K decreases slowly with temperature. This seems to be due to the temperature variation of λ
3, since the thermal conductivity of powdered Al
2O
3 (1.0g/cm
3) increases slowly with temperature.
(3) For the enthalpy change of the oxidation of UO
2, the following values were obtained.
UO
2+1/6 O
2→1/3 U
3O
7Δ
H1=-13.8±1.5 kcal/mol (230°C)
1/3 U
3O
7+1/6 O
2→1/3 U
3O
8Δ
H2=-10.8±1.3 kcal/mol (380°C)
Δ
H1 (230°C)+Δ
H2 (380°C)=-24.6±2.8 kcal/mol agrees fairly well with the published value, Δ
H(25°C)=-25.30 kcal/mol and Δ
H (380°C)=-25.12 kcal/mol, for the reaction, UO
2+1/3 O
2→1/3 U
3O
8.
(4) A part of the deviation of the value of
K comes from the non-uniformity of mixing, the deviations of ρ
s and λ
3 due to the tapping method, the errors in the values of Δ
H of the standard reactions and the other experimental errors. However, these will be less than several percent.
(5) λ
3 during reaction is considered to be different from the static thermal conductivity, then
K will be influenced by the type of reaction. This effect will occupy the greater part of the deviation of
K, so it is desirable to calibrate
K by the same type of reaction.
(6) Enthalpy change of the oxidation of UO
2 was also obtained preliminarily by the measurement of specific heat of UO
2 during heating in air. The values thus obtained, Δ
H1=-12.8 kcal/mol (230°C) and Δ
H2=-11.0 kcal/mol (380°C) agree fairly well with the D. T. A. results.
The authors wish to thank Dr. Keiichi Oshima for his helpful discussion. They are also indebted to Dr. Toshio Nakai and Dr. Kenjiro Kimura for their continuing encouragement during this study.
抄録全体を表示