Journal of Ion Exchange
Online ISSN : 1884-3360
Print ISSN : 0915-860X
ISSN-L : 0915-860X
Volume 27, Issue 3
Displaying 1-5 of 5 articles from this issue
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  • Akira MONKAWA, Kyoko FUJII, Tomoe NAKAGAWA, Tomoko GESSEI, Yuki TAKIMO ...
    2016 Volume 27 Issue 3 Pages 53-56
    Published: September 25, 2016
    Released on J-STAGE: September 21, 2016
    JOURNAL FREE ACCESS

    Powders of LiNbO3 have been synthesized by a wet-chemical method. The Nb precursor solution was obtained as a clear colorless solution when hydrated niobium oxide was dissolved in tetramethylammonium hydroxide solution at 80°C for 2 h. The Nb-cluster in the solution was characterized by electrospray-ionization mass spectrometry and infrared spectroscopy and was found to be TMA6[H2Nb6O19]. The LiNbO3 precursor solution was obtained by Li/TMA ion exchange during mixing of the Nb precursor solution and the LiOH solution. The precursor solution was calcined in a muffle furnace at 300–800°C for 5 h. The crystal structures and the Nb/Li ratio of the obtained LiNbO3 powders were characterized by X-ray diffraction and photoelectron spectroscopy. These showed that our low temperature (400°C) synthesis obtained crystalline LiNbO3 powders with a stoichiometric composition and without the presence of any organic substances.

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  • Tetsuto KAJIYAMA, Shohei SAKAI, Jun INOUE, Toru YOSHINO, Satoshi OHMUR ...
    2016 Volume 27 Issue 3 Pages 57-62
    Published: September 25, 2016
    Released on J-STAGE: September 21, 2016
    JOURNAL FREE ACCESS

    The synthesis of metal ion adsorbents from modified banana fibers comprising a Schiff base was investigated. The adsorption properties of a metal ion adsorbent were evaluated, and banana fiber (BF)-g-(glycidyl methacrylate)(GMA)(BF-GMA) were synthesized. A Schiff base 2,2’-{iminobis[ethane-2,1-diylnitrilo(E)methylidine]}bisphenol was synthesized via a reaction of diethylenetriamine and 5-bromo-salicyialdehyde in methanol. A metal ion adsorbent (BF-GMA(Br)) was synthesized via a reaction of the Schiff base with BF-GMA. Over 90% of La3+, Gd3+, Tm3+, Pr3+, Tb3+, Yb3+, Nd3+, Dy3+, Lu3+, Sm3+, Ho3+, Eu3+, and Er3+ were adsorbed in a pH range of 6.0–6.6 by the synthesized metal ion adsorbent. Almost 100% of In3+ at a pH value of 3.0–4.0 and 95% of Ga3+ at a pH value of 3.9 were absorbed, thereby showing the maximum adsorption percentage. Almost 15% and 25% of In3+ was adsorbed at a pH value of 1.4–1.6 and 1.8, respectively. Adsorption of Ga3+ was barely observed in the pH range of 1.4–1.8. These results show that banana fibers can be utilized as metal ion adsorbents.

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