The speciation of organic carbon (OC) and elemental carbon (EC) are measured on source and ambient quartz-fiber filter samples by several thermal-optical carbon analysis methods. The split between OC and EC is defined based on combinations of combustion temperatures, residence time at each temperature, the composition of the atmosphere, helium or helium plus oxygen, surrounding the sample, and light reflected from the filter. In the last several years, the world has experienced a supply shortage and large cost increase for helium. This investigation demonstrated that using nitrogen instead of helium as the carrier gas provided equivalent measures of total carbon (TC), OC, and EC for authentic samples. The determination accuracies were verified by analyzing sucrose solutions for calibration standards, spark graphite (GFG 1000) for EC samples, the National Institute of Standards and Technology (NIST) SRM 1648a for urban dust, SRM 1650a/2975for diesel exhaust, the National Institute for Environmental Studies (NIES) CRM No. 8 for automotive exhaust in tunnels, and CRM No. 28 for urban aerosol in Beijing. Using nitrogen instead of helium yielded equivalent TCs for authentic samples within the electric microbalance errors that would be introduced by electrical charging of dust samples. However, the carbon fractions (i.e., OC/EC splits, or OC1, OC2…) were not well reproduced for several samples for this investigation. More data sets need to be analyzed to evaluate the use of the source and ambient samples.
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