Inductively coupled plasma mass spectrometry (ICP-MS) is widely used when rapid and sensitive detection for a wide range of elements of airborne particles is required in many situations. However, when conventional ICP-MS equipped with a quadrupole mass spectrometer (ICP-QMS) was used for a detailed study on the signal fine structure with scanning-based mass spectrometers, simultaneous multi-element measurements could not be applied. In order to further improve time resolution of the ICP-QMS and to extend its capabilities to determine single particle information, ICP-MS equipped with the Time-of-Flight Mass Spectrometer (ICP-TOFMS) was developed recently. This study presents the application of real-time measurements for elements in particles using ICP-TOFMS. This technique is demonstrated to detect phosphorus, sulfur, and halogen elements, such as engine oil additive elements.
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