A novel metallic monolith anodic
γ-alumina catalyst, prepared through anodization of aluminum, hot water treatment and active metal impregnation, was employed to investigate the selective catalytic reduction of NO under oxygen-rich conditions with propene and diesel fuel as reducing agents.
Using propene as a reducing agent, Pt/Al
2O
3/Al offered the best low-temperature SCR activity (about 573 K), and was resistant to SO
2 poisoning. However, a high undesired selectivity to N
2O and a narrow operating-temperature window were two major disadvantages. At a moderate temperature (about 673 K), Cu-Ce/Al
2O
3/Al showed a favorable de-NO
x activity comparable to Pt/Al
2O
3/Al, a higher N
2 selectivity and a wider operating-temperature window than Pt/Al
2O
3/Al. In particular, adding SO
2 into feedstream dramatically promoted the de-NO
x activity of Cu-Ce/Al
2O
3/Al, and this increase was unchanged with time-on-stream. Among the catalysts tested in this paper, the highest de-NO
x activity was obtained on the alumite support, but at a high temperature (about 773 K). Although the presence of SO
2 strongly inhibited the NO
x reduction of the alumite support, NO
x conversion of 80% could still be maintained in the coexisting SO
2 and H
2O.
When introducing diesel fuel instead of propene as a reducing agent, the over-oxidation of diesel fuel by oxygen remarkably decreased the NO
x reduction of Pt/Al
2O
3/Al and Cu-Ce/Al
2O
3/Al. The alumite support became a promising choice, due to the stable 67% of de-NO
x activity achieved under the same redox conditions. However, the presence of a high concentration of SO
2 substantially depressed the de-NO
x activity of the alumite support. On the contrary, a significant promotional effect of SO
2 on the de-NO
x activity was also observed over Cu-Ce/Al
2O
3/Al, when using diesel fuel as a reducing agent, as observed in the SCR-NO-C
3H
6.
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