-
Chu-Wan HONG
1996 Volume 104 Issue 1213 Pages
793-795
Published: September 01, 1996
Released on J-STAGE: August 06, 2010
JOURNAL
FREE ACCESS
The discrete element method (DEM) has been used to simulate the influences of ζ-potential on the particle packing structures during centrifugal casting of submicron alumina powders. The long-range potential interactions according to the DLVO theory have been implemented into the DEM simulation program. While well-stabilized suspensions with high ζ-potential tend to form particle chains, suspensions with low ζ-potential form agglomerate structures. The mechanism of particle clustering is discussed.
View full abstract
-
Ding-Fwu LII, Jow-Lay HUANG, Kuo-Chi TWU, Ai-Kang LI
1996 Volume 104 Issue 1213 Pages
796-801
Published: September 01, 1996
Released on J-STAGE: August 06, 2010
JOURNAL
FREE ACCESS
Alumina composites containing two different sizes and various compositions of Cr
3C
2 were pressurelessly sintered at 1550°C for 2h in a purified Ar atmosphere. The chemical stability of chromium carbide, microstructure, densification and mechanical properties were studied. The phase stability of Cr
3C
2 was found quite sensitive to the temperature and oxygen content in the sintering environment. The addition of Cr
3C
2 played an important role in the grain growth of alumina. Coalescence of Cr
3C
2 was observed along the grain boundaries of alumina in samples containing high Cr
3C
2. By controlling the phase stability, and the amount and particle size of Cr
3C
2, a flexural strength of 500MPa, 57% enhancement, was obtained.
View full abstract
-
Yutaka KAGAWA, Subashi C. KHATRI, Michael J. KOCZAK
1996 Volume 104 Issue 1213 Pages
802-807
Published: September 01, 1996
Released on J-STAGE: August 06, 2010
JOURNAL
FREE ACCESS
Al
2O
3/Al alloy hybrid composites (SiC/Al
2O
3/Al alloy hybrid composite) reinforced with chopped and continuous SiC fiber (Nicalon
TM) have been fabricated by directed metal oxidation of Al-Mg-Si alloys. Effects of additive elements, Mg and Si on the in situ formation of SiC/Al
2O
3/Al alloy composites were studied. In situ infiltration of the Al
2O
3/Al alloy composite phase into the SiC fiber was possible only when a small quantity of Mg (5 mass%) was used. No infiltration was observed for 10 mass% Mg alloys. Composites fabricated from Al⋅5Mg⋅5Si and Al⋅5Mg⋅10Si alloys showed incorporation of Al
2O
3/Al alloy composite into the SiC fibers. The silicon content of the alloy affected the fabrication of the composite by altering the growth rate of the oxide, and the fastest fabrication of the composite was possible using Al⋅5Mg⋅5Si alloys. It was concluded that aluminum alloys of lower Mg contents (<5 mass%) are recommendable as a starting aluminum alloy for the incorporation of Al
2O
3/Al alloy composite phase into the SiC fibers with void free structure. However, degradation of the fiber during incorporation should be considered the application of this process.
View full abstract
-
Shigeki SAKAGUCHI, Shin-ichi TODOROKI
1996 Volume 104 Issue 1213 Pages
808-811
Published: September 01, 1996
Released on J-STAGE: August 06, 2010
JOURNAL
FREE ACCESS
Oxyfluoride glass in the system Na-Mg-Si-O-F, which exhibits lower Rayleigh scattering than silica glass, has been developed. The glass forming region is extended for an F content of up to 30% of the anions. Scattering measurements for (1-
x)(Na
2O⋅2SiO
2)-
xMgF
2 glasses revealed that the scattering intensity decreases to 70% of the intensity of silica glass for a MgF
2 content of 5mol%. The factors affecting scattering were evaluated based on glass properties such as refractive index dispersion parameters and glass transition temperature. The results suggest that the scattering in this glass is dominated by the density fluctuation.
View full abstract
-
Masaki NARISAWA, Hajime TAKAO, Junpei HOSHINO, Kiyohito OKAMURA, Masay ...
1996 Volume 104 Issue 1213 Pages
812-815
Published: September 01, 1996
Released on J-STAGE: August 06, 2010
JOURNAL
FREE ACCESS
Amorphous carbon in membrane form containing a small amount of silicon uniformly in the structure was prepared by firing a new organosilicon precursor, poly (phenylsilylene)-ethynylene-1, 3-phenylene-ethynylene (MSP). The pyrolyzed products look like glassy carbon. The cross-linking processes before pyrolysis were effective to keep its shape during the heat treatment and were influenced by oxygen in an ambient atmosphere during cross-linking processes. The oxygen introduced into the precursor enhanced the cross-linking but decreased the residual weight after the pyrolysis. In the pyrolyzed products, silicon atoms appeared to distribute uniformly from the outer surface to interior core. The structure of the products was amorphous, but β-SiC precipitated beyond 1873K.
View full abstract
-
Young-Wook KIM, Mamoru MITOMO, June-Gunn LEE
1996 Volume 104 Issue 1213 Pages
816-818
Published: September 01, 1996
Released on J-STAGE: August 06, 2010
JOURNAL
FREE ACCESS
Densification of SiC with oxide additives is affected mainly by the amounts of free C and SiO
2 contained in the starting powders. In this study, the influence of oxidation of starting powders on densification was investigated. Oxidation of SiC powders, prior to liquid phase sintering, increased the oxygen content and decreased the carbon content remarkably, and led to higher sintered density for both α- and β-SiC. Higher sintered density was attributed to the formation of liquid at lower temperatures and the suppression of reactions between the free C and oxide additives.
View full abstract
-
Nobuyuki KOURA, Arihiro TANIGUCHI, Hiromasa SHOJI, Shigeru ITO, Yoshin ...
1996 Volume 104 Issue 1213 Pages
819-822
Published: September 01, 1996
Released on J-STAGE: August 06, 2010
JOURNAL
FREE ACCESS
The preparation of high-
Tc superconducting magnetic shielding by the electrophoretic deposition method has been investigated. The calcined YBCO powder was suspended in an acetone bath, and was deposited on various cylindrical substrates of silver, stainless steel, ceramics and permalloy. The sample deposited with oxides particles was sintered at 920°C for 1h, and then annealed at 500°C for 1h. The magnetic attenuation ratio (
Hin/
Hex) was measured at 77K. All samples with silver, stainless steel, ceramics, or permalloy substrate were able to shield the ambient magnetism (0.5Oe) at least. The magnetic shield on a silver substrate with the diameter of 15mm and length of 30mm had the attenuation ratio of 5.1×10
-4 at 7.6Oe.
View full abstract
-
Takatoshi KIMURA, Masahiko NAKAMURA
1996 Volume 104 Issue 1213 Pages
823-827
Published: September 01, 1996
Released on J-STAGE: August 06, 2010
JOURNAL
FREE ACCESS
This investigation is undertaken to discuss the influence of the structure of aggregates, interparticle interaction and particle shape on the spinnability of slurry. An increase of viscosity of glass bead model slurry in which the interaction among model flocs is negligible tends to decrease the spinnability. On the other hand, the interaction among kaolin particles increases, the spinnability of kaolin slurry in which the interaction among particles is extremely strong. The strong effect of orientation of needle-like kaolin particles on the spinnability is found experimentally. It is found that the orientation of needle-like kaolin particles affects the spinnability significantly.
View full abstract
-
Seiji HAYAMA, Masakuni OZAWA, Suguru SUZUKI
1996 Volume 104 Issue 1213 Pages
828-831
Published: September 01, 1996
Released on J-STAGE: August 06, 2010
JOURNAL
FREE ACCESS
Fracture energy and
R-curve behavior of β′-Sialon-BN composites were investigated to elucidate the strength degradation caused by thermal shock. The fracture energy and
R-curve behavior were obtained from compliance analysis on the load-displacement curves of the quasi-static fracture of 3-point bend specimen with chevron-notch. The critical temperature difference of strength degradation (
ΔTc) for the composite containing 30mass% BN was 700K and 900K for
Z=1.0 and 2.0 (Si
6-zAl
zO
zN
8-z), respectively. These
ΔTc results agree well with the values calculated from Hasselman's equation. The steep reduction of strength by thermal shock and the disappearance of
R-curve behavior were observed on the same thermal shock temperature difference
ΔT. The relationship between the ratio of effective fracture energy to elastic fracture energy (γ
eff/γ
i) and retained strength was found to be roughly linear. It was presumed that the residual stress from thermal shock influences the crack-face contact shielding mechanism in the composites and is a possible inhibition factor to forming of the
R-curve effect.
View full abstract
-
Effect of Various Organic Compounds on the Carbonation of the Basic Calcium Carbonate
Hisao SUGIHARA, Ken-ichiro ONO, Kentaro ADACHI, Yukako SETOGUCHI, Tats ...
1996 Volume 104 Issue 1213 Pages
832-836
Published: September 01, 1996
Released on J-STAGE: August 06, 2010
JOURNAL
FREE ACCESS
The addition of amines such as ethylenediamine, diethylenetriamine and meramine in the course of carbonation of basic calcium carbonate promoted the formation of a disk-like calcium carbonate which is vaterite and 1-1.5μm in diameter and 0.1-0.2μm in thickness. On the other hand, dicarboxylic acids, carboxylic chelate compounds, and amino acids promoted the formation of cubic or spindle-like calcite. Diethylenetriamine which was adsorbed on the surface of calcium carbonate plays an important role in the formation of disk-like calcium carbonate.
View full abstract
-
Takeo TOKIAI, Takashi UESUGI, Yuji ETON, Satoshi TAMURA, Yasuhiro YONE ...
1996 Volume 104 Issue 1213 Pages
837-843
Published: September 01, 1996
Released on J-STAGE: August 06, 2010
JOURNAL
FREE ACCESS
Semiconducting ceramics of p-type bismuth telluride was fabricated by plasma sintering using milled powders of (Bi
2Te
3)
0.25(Sb
2Te
3)
0.75+Se2.0mass%. The figure of merit and compressive strength were as large as 2.7×10
-3K
-1(25°C) and 6MPa, respectively. Their thermoelectric properties did not exhibit anisotropy due to their isotropic microstructure without grain orientation. The power factor increased with increasing sintering temperature and pressure, and was independent of the sintering time. Thermoelectric properties apparently have been generated possibly due to enhanced cleaning and activity of milled powder by spark plasma effect.
View full abstract
-
Keizaburo KURAMASU, Shinji SAITO, Kazuyuki OKANO, Yasutaka TAKAHASHI
1996 Volume 104 Issue 1213 Pages
844-849
Published: September 01, 1996
Released on J-STAGE: August 06, 2010
JOURNAL
FREE ACCESS
In order to develop an economical production process of stable and uniform thin film resistors, the RuO
2-based thin films prepared by MOD were studied with focussing on the three major factors to affect the properties of the RuO
2 resistors: the kinds of the substrate, suitable resin component for screen printing and effect of the cleanness of the substrate. As a result, it was found that (1) the films formed on amorphous glazed alumina plate were much more thermally stable than those on crystalline glazed plate, (2) rosin type paste with higher temperature thermal decomposition property gave better resistance uniformity than cellulose type paste, and (3) cleaning the substrate surface with fumed nitric acid was indispensable for making realization of the uniformity and reproducibility in the resistance of RuO
2 dot array. Studies on the properties of sputtered RuO
2 films were also made for comparison with the properties of MOD RuO
2 films.
View full abstract
-
Kazuaki YOSHIDA, Tsuguo SATOH, Hiroshi HIHARA, Masato OKU
1996 Volume 104 Issue 1213 Pages
850-853
Published: September 01, 1996
Released on J-STAGE: August 06, 2010
JOURNAL
FREE ACCESS
A CIP hybridized process for fabrication of a single-mode optical fiber with a small core eccentricity error has been studied. As a result, a process for fabrication of an optical fiber with a core eccentricity error of less than 0.3μm has been developed. In this study, we also clarified the following. (1) A hybridized soot preform with an outer diameter noncircularity of less than 0.4% was prepared by packing granular silica particles with a high packing density into a rubber mold with a thick wall. (2) A soot preform with a noncircularity of less than 0.06% and an outer diameter fluctuation of less than 0.11mm was made by means of a grinding treatment in which the outer surface of the soot preform was ground around a core rod. (3) A single-mode optical fiber with a core eccentricity error of less than 0.3μm was also fabricated from the soot preform ground above.
View full abstract
-
Taiji MATSUMOTO, Fumio ISO, Yoshiaki GOTO
1996 Volume 104 Issue 1213 Pages
854-857
Published: September 01, 1996
Released on J-STAGE: August 06, 2010
JOURNAL
FREE ACCESS
Zeolite A was synthesized at 80°C from allophane in NaOH-KOH mixed solution. Single phase of zeolite A was obtained from mixed solutions with Na/Na+K molar ratios larger than 0.8. In the range between 0.6 and 0.8 for mole fraction of Na, chabazite type zeolite (K-G) and linde F(K-F) coexisted with zeolite A. Zeolite A did not form from mixed solutions with the mole fraction of Na less than 0.6. The rate of formation of zeolite A decreased with decreasing mole fraction of Na, which was explained by the decreases in nucleation rate and liner crystal growth rate. The crystal size of zeolite A increased with an increase in the K content in the mixed solutions.
View full abstract
-
Akio NISHIDA, Yasuhiko KOHTOKU
1996 Volume 104 Issue 1213 Pages
858-862
Published: September 01, 1996
Released on J-STAGE: August 06, 2010
JOURNAL
FREE ACCESS
The effects of atmospheres on foaming characteristics and properties of perlite were investigated. The foaming characteristics and properties of perlite were influenced by the thermal conductivity of the heating gas and the presence of oxygen in the heating atmosphere. The release temperature of H
2O in perlite was shifted to the higher temperature region by a rapid heating. In order to accelerate the heating rate of perlite, He gas with a high thermal conductivity was used for a heating atmosphere. It was found that the unit weight of perlite expanded by heating in He gas was smaller than that in a gas with a moderate thermal conductivity such as N
2. The unit weight of perlite expanded by heating in an oxidizing gas was larger than that in an inert gas. In the case of heating at 900°C which was near a softening temperature of perlite, the inhibition effect of oxygen on foaming characteristics was observed remarkably. This is because that the softening temperature is increased due to the oxidation of the glass phase.
View full abstract
-
Kanji TANAKA, Tetsuji YANO, Shuichi SHIBATA, Masayuki YAMANE
1996 Volume 104 Issue 1213 Pages
863-866
Published: September 01, 1996
Released on J-STAGE: August 06, 2010
JOURNAL
FREE ACCESS
Cu
+-containing calcium phosphate glasses have been prepared by remelting Cu-containing glass (a) under a controlled atmosphere of low oxygen pressure, and (b) with silicon powder as a reducing agent. About 96% of copper became cuprous ion by remelting under an oxygen partial pressure of 10
-10Pa at 1400°C for 8h. However, further reduction of oxygen pressure was not effective but led to the vaporization of phosphor, resulting in an increase in the devitrification tendency of the melt. Remelting with silicon powder was much more effective in reducing Cu
2+ to Cu
+ state. More than 99% of copper could be reduced to cuprous state by the remelting at 1250°C for 0.5h when the ratio of silicon to copper, Si/Cu, was equal to 2.5 or larger. The emission intensity from the Cu
+-containing glass became maximum when Si/Cu=2.5.
View full abstract
-
The Role as a Seed of Ball Abrasion Powder in Vibration Milling
Yu-ichi YOSHIZAWA, Fumio SAITO
1996 Volume 104 Issue 1213 Pages
867-871
Published: September 01, 1996
Released on J-STAGE: August 06, 2010
JOURNAL
FREE ACCESS
Effect of wet grinding of commercial aluminum hydroxide on the transformation to α-alumina during heating was investigated using vibration ball mill. The grinding with high purity alumina balls reduced the transformation temperature to α-alumina by 300°C. Such significant reduction in the transformation temperature was not observed in the samples obtained by the grindings with zirconia and low purity alumina balls. The formation of α-alumina from ground aluminum hydroxide at such a low temperature was possibly attributed to a seed-effect of fine α-alumina powder worn from the balls and its uniform mixing with the mother powder during grinding. The α-alumina powder made from ground aluminum hydroxide consisted of very fine particles, which enabled us to sinter at a relatively low temperature. The sintered bodies had fine-grained structure without abnormal grain growth.
View full abstract
-
Byung-Nam KIM, Yumiko KATSUKAWA, Byung-Wook AHN, Manabu ENOKI, Teruo K ...
1996 Volume 104 Issue 1213 Pages
872-876
Published: September 01, 1996
Released on J-STAGE: August 06, 2010
JOURNAL
FREE ACCESS
Fracture resistance behavior with respect to crack extension is evaluated from indented strengths for both alumina and alumina matrix composite dispersed with 10% SiC particles. Since residual stresses due to the thermal expansion mismatch between SiC particle and Al
2O
3 matrix are expected to be exerted on crack surfaces regardless of crack length, the fracture resistance are assumed to be dependent on the square root of crack extension according to fracture-mechanical predictions.
R-curves are obtained from the linearity between Vickers-indented strength and α
f-1/2, where α
f is the critical crack length. A nearly constant fracture resistance curve is obtained for the alumina, while rapidly increasing fracture resistance for the composite. The fracture toughnesses measured independently by the controlled surface flaw method are consistent with the obtained fracture resistance. The role of residual stresses is discussed as a characteristic parameter for the fracture resistance of particle-dispersed composites. In addition, the technical aspects during the evaluation process of
R-curve are also discussed.
View full abstract
-
Toyohiko SUGIYAMA, Tatsuro HORIUCHI, Toshihiko OSAKI
1996 Volume 104 Issue 1213 Pages
877-881
Published: September 01, 1996
Released on J-STAGE: August 06, 2010
JOURNAL
FREE ACCESS
Two methods for evaluating absorption coefficients of porcelain bodies in the visible wavelength range were proposed and applied to Japanese porcelain. The comparative merits of the methods were discussed. Apparent absorption coefficients could be obtained more precisely than conventional ones by measuring the transmittances for different sample thicknesses. Variations in translucency due to compositional change of the porcelain bodies could be explained quantitatively using these coefficients. The scattering and absorption coefficients of bodies were calculated from their reflectances and transmittances using the Kubelka-Munk equations. The accuracy of these coefficients was lower than that of the apparent absorption coefficient because of difficulties in the transmittance measurements. Nevertheless these coefficients were very useful for understanding the optical properties of porcelain bodies. The relationship between the reflectance and scattering coefficient of bodies was also discussed.
View full abstract
-
Kazuya MORI
1996 Volume 104 Issue 1213 Pages
882-885
Published: September 01, 1996
Released on J-STAGE: August 06, 2010
JOURNAL
FREE ACCESS
The influence of bridging characteristics on the fracture strength of ceramics was investigated by numerical simulation. Factors influencing the fracture strength of ceramics include the defect size, bridging characteristics and the fracture toughness. The relationship between defect size and fracture strength has been studied by many researchers. However, there are few reports on the relationship between bridging characteristics and fracture strength, though this relationship is important for materials development. The purpose of the present investigation was to reveal the relationship between the bridging characteristics and the fracture strength of ceramics by numerical simulation. In the numerical simulation, the stress intensity factor at crack tip and the fracture toughness were used for the fracture criterion. It is assumed that the crack propagates when the crack-tip stress intensity factor reaches the fracture toughness. The effect of bridging on the toughening is not expected when the defect size as an equivalent crack length is smaller than 20 to 50μm. The reason is that the stable crack extension with bridging before a catastrophic fracture is very short for defects smaller than 20 to 50μm.
View full abstract
-
Masahiko NAKAMURA, Takahiro FUKUSHIMA
1996 Volume 104 Issue 1213 Pages
886-891
Published: September 01, 1996
Released on J-STAGE: August 06, 2010
JOURNAL
FREE ACCESS
The suitable levels of fabrication factors such as the content (
F/C) of the fine aggregates, the content (
Vf) of the vinylon toughening fibers and the surface modification of the fibers for new development of the non-asbestos fiber-reinforced cement board (FRCB) having an excellent mechanical or a frost durable properties were determined. The values of
F/C=0.5mass% and
Vf=2.0vol% were the best for the mechanical properties of the FRCBs. The hydrophilic surface modification of the fibers was also effective to improve the mechanical properties due to an enhancement of the interfacial adhesion between hardened cement matrix and fibers. The frost durability was more effectively improved by the controlling of the pore size distribution than the surface modification of the fibers.
View full abstract
-
Nobuyuki TAMARI, Isao KONDOH, Takahiro TANAKA, Nobuyuki TOKUNAGA, Kazu ...
1996 Volume 104 Issue 1213 Pages
892-896
Published: September 01, 1996
Released on J-STAGE: August 06, 2010
JOURNAL
FREE ACCESS
Alumina matrix composites mixed with titanium carbide whiskers up to 30vol% were fabricated by hot-pressing at 1600°C under 30MPa for 30min. Two kinds of titanium carbide whiskers having different diameters were used as a reinforcing agent. Mechanical properties, oxidation resistance and cutting perfomance for cast iron were studied. The addition of thin whiskers had a tendency to obstruct the densification of composite body. However, bending strengths at room temperature and 1000°C and oxidation resitance of the composites containing thin whiskers were higher than those of the composites containing thick whiskers. On the other hand, no remarkable difference in Vickers hardness and fracture toughness was observed concerning to the effect on the whisker diameter. The composites containing thin whiskers showed the cutting performance superior to those containing thick whiskers.
View full abstract
-
Qi FENG, Kazumichi YANAGISAWA, Nakamichi YAMASAKI
1996 Volume 104 Issue 1213 Pages
897-899
Published: September 01, 1996
Released on J-STAGE: August 06, 2010
JOURNAL
FREE ACCESS
Birnessite-type lithium manganese oxide was obtained directly by reacting a Mn(NO
3)
2 solution with a mixed solution of H
2O
2 and LiOH at room temperature. The manganese oxide was characterized by X-ray, DTA-TG and chemical analysis. The manganese oxide had a layered structure with a single sheet of crystal water and lithium ions between two-dimensional edge-shared MnO
6 octahedral sheets. The basal spacing along the c-axis was 0.713nm. The lithium ions in the interlayer space were ion-exchangeable with Na
+ and K
+, but partially with Mg
2+.
View full abstract
-
Yukiko FURUKAWA, Osamu SAKURAI, Kazuo SHINOZAKI, Nobuyasu MIZUTANI
1996 Volume 104 Issue 1213 Pages
900-903
Published: September 01, 1996
Released on J-STAGE: August 06, 2010
JOURNAL
FREE ACCESS
The relationship between the grain growth and the wettability of grains by a liquid phase was discussed on the basis of the observation of the microstructure of La-doped SrTiO
3 ceramics and the measurement of the contact angle of the liquid phase (Sr
1Ti
3.206La
0.328O
7.904) on the SrTiO
3 substrate using the sessile drop method. The contact angle of the liquid phase in SrTiO
3, which was the composition at 1490°C as determined from the SrO-TiO
2 phase diagram, on the SrTiO
3 substrate was 22°. The contact angle of the liquid phase containing La
2O
3 was 22°. The contact angles of the liquid phases in the cases of SrTiO
3 containing SiO
2 and a mixture of SiO
2 and Bi
2O
3 were 16° and 9°, respectively. The contact angle was decreased by the addition of SiO
2 and/or Bi
2O
3. The liquid phase of La-doped SrTiO
3 ceramics was considered to have relatively poor wetting and to localize at the triple grain junctions at high temperatures and then to be exuded from the inner part to the surface of the samples during cooling. The nucleation and grain growth occur at this spot where the liquid phase is present. Thus, exaggerated grain growth occurs. The number of nuclei increases with the increase of the volume of liquid phase upon increasing the Ti/Sr ratio, which leads to the inhibition of grain growth. On the other hand, since the liquid phase of La-doped SrTiO
3 containing SiO
2, Bi
2O
3 can uniformly wet the grains, the growth rates of all grains are almost the same and exaggerated grain growth is not observed.
View full abstract