In the previous report (Jiro Matsuda and Ryoichi Tanaka, this journal,
76, 94 (1968)), photochemistry of NaI doped sodiumsilicate glasses has been discussed and it's reaction mechanism, cage effects of the glass matrix and the influence of iodine ion upon the growth of color centers in the glasses have been illustrated.
In the present report, the writers made comparative studies on the alkalisilicate glasses (Li
2O-3SiO
2, Na
2O-3SiO
2, and K
2O-3SiO
2).
The results are as follows,
1) excepting F
-, halogen ions in the alkalisilicate glasses are photo-oxidized to X
2- type (dihalogen ion) with the irradiation of U. V. or X-ray and the photo-oxidation tendency for each halogen ion is great as following order, Cl
-<Br
-<I
-.
2) dihalogen ions produced in the glasses are stable at room temperature in a dark room and their absorption bands are 380, 715mμ (I
2-), 360mμ (Br
2-) and nearly 350mμ (Cl
2-), that is, the wave-lengths of their absorption bands are independent of the kind of alkali components in the glasses.
3) the more acidic is the glass, the halogen ion doped in the glass is the more easily photo-oxidized, and such produced dihalogen ion is the more stable.
4) it is difficult for iodine to dissolve in Li
2O-3SiO
2 glass as I
-, consequently, in this glass, the yield of I
2- by photochemistry is small though lithia glass is the most acidic compared with other alkalisilicate glasses.
5) excepting F
-, halogen ions have suppression effects on the growth of glass color centers induced by U. V. or X-ray irradiation, but the 310mμ band of the color centers in alkalisilicate glasses is comparatively difficult to be suppressed, and rather strengthend in the case of KBr doped K
2O-3SiO
2 glass.
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