Mullite specimens were subjected to corrosion at high temperatures by alkaline (Na
2CO
3) vapor and many kinds of reaction products were formed containing corundum, nepheline, carnegieite, carnegieite-sodium aluminate solid solution and sodium aluminate.
In the first stage of the corrosion process, mullite decomposed into carnegieite and corundum. As the supply of alkaline vapor was continued, the latter gradually changed into sodium aluminate, which in turn dissolved into carnegieite to form carnegieite-sodium aluminate solid solution.
In the low content of sodium aluminate, that solid solution could be converted, on cooling, to nepheline structure like as the case with pure carnegieite. With increasing amount of sodium aluminate, it was found to disturb this conversion and to stabilize the solid solution as carnegieite.
The final crystalline product by the corrosion was sodium aluminate. However, after a long time of exposure to the alkaline vapor, this phase gradually changed into glassy phase resulting in the wear of mullite refractory.
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