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41 巻 , 2 号
選択された号の論文の9件中1~9を表示しています
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  • 芦田 玉一
    41 巻 (1999) 2 号 p. 105-111
    公開日: 2010/09/30
    ジャーナル フリー
    入門講座「結晶学の原点を読む」の第4回目は, 直接法の原点となったD.Sayreの論文を取り上げました.結晶構造解析は, ごく限られた専門家達の研究対象かつ独占的道具でした.それが, 物質研究者すべてに便利な道具として認知され, また必須な手法となったのは, 測定法の進歩 (自動回折計の出現) ・大規模計算の可能化 (コンピュータの進歩) を挙げることができますが, まず何よりも大きなブレークスルーは「位相問題」が解決したことと言えましょう.我々が測定できる結晶面からの散乱強度の情報は, その絶対値だけで位相の情報が顕には含まれていません.多くの結晶面からの散乱強度を数学的に処理し, 不等式関係を持ち込むことにより位相の情報を得ていく方法は, 直接法として知られています.直接法確立へ大きな貢献をした, J.KarleとH.Haupmannに対し, 1985年ノーベル化学賞が授与されています.しかし位相問題の解決は決してこのお二人だけの業績ではなく, 何人もの結晶学者の研究の積み重ねの上に成り立つものと言えましょう.この欄では, 単純平易な発想から利用頻度の高い位相関係式を導いたSayreの論文を基に, 直接法の基礎も含めて解説していただきます.
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  • 高田 昌樹
    41 巻 (1999) 2 号 p. 112-121
    公開日: 2010/09/30
    ジャーナル フリー
    Endohedral metallofullerenes are novel forms of fullerene-related materials, which encage metal atom inside a carbon cage. The recent X-ray structural studies of metallofullerenes, Sc@C82 and Sc2@C84, by the synchrotron powder diffraction experiment are presented to illustrate the usefulness of the MEM/Rietveld analysis, which is a self-consistent iterative way in combination with the MEM (Maximum Entropy Method) and Rietveld analyses. The obtained MEM charge densities clearly reveal the distinct features of encapsulated metals inside the fullerene cages as well as endohedral cage structures for Sc@C82 and Sc2@C84.
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  • 原田 一明
    41 巻 (1999) 2 号 p. 122-128
    公開日: 2010/09/30
    ジャーナル フリー
    Crystal structures of turkey and human lysozymes were refined at atomic resolution by full-matrix least-squares method with anisotropic temperature factors. The refinement converged at the R-value of 0.104 for turkey lysozyme and 0.115 for human lysozyme at 1.12 Å and 1.15 Å resolution, respectively, and the estimated r.m.s. coordinate errors for respective pro-teins were 0.031 Å and 0.034 Å. The magnitude and the degree of anisotropy of the atomic thermal motion have strong positive correlation with the square of distance from the molecular centroid. The statistical analysis suggested that such characteristics of anisotropic thermal motion are ascribed to the rigid-body rotation and local motions rather than the breathing motion.
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  • 中津 亨
    41 巻 (1999) 2 号 p. 129-135
    公開日: 2010/09/30
    ジャーナル フリー
    The crystal structure of Eschelichia coli asparagine synthetase has been determined by X-ray diffraction analysis. The overall structure of the enzyme is remarkably similar to that of the catalytic domain of yeast aspartyl-tRNA synthetase despite low sequence similarity (11%) . These enzymes have a commom reaction mechanism that implies the formation of an aminoacyl-adenylate intermediate. The active site architecture and most of the catalytic residues are also conserved in both enzymes. These proteins have probably evolved from a common ancester even though their sequence similarities are small.
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  • 熊田 伸弘, 木野村 暢一
    41 巻 (1999) 2 号 p. 136-140
    公開日: 2010/09/30
    ジャーナル フリー
    We review preparations and crystal structures of various kinds of new niobium oxides. Ilmenite-type ANbO3 (A=Li, Na), which were prepared by low temperature hydrothermal reaction and ion-exchange reaction, are the first examples of ilmenite-type niobium oxides. These niobium oxides are metastable phases and transform into the stable phases at elavated temperatures. A new reduced niobium oxide, Rb1.51Nb10O17 has a Nb6O12 cluster characteristic of strongly reduced niobium oxides. Weakly reduced niobium oxides, K2YNb5O15-δ and K6Nb10.9O30 have NaNb6O15F-type and tetragonal tungsten bronze type strcutures, respective-ly. In the A2O-MO- Nb2O5 (A=K, Rb, Cs; M=Mg, Fe) system, two types of compounds K2M2Nb4O13 and A (M, Nb) 2O5, which are isostructural with K2Ti6O13 and KTiNbO5 respectively, were obtained.
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  • 内田 正哉, 堀内 繁雄
    41 巻 (1999) 2 号 p. 141-145
    公開日: 2010/09/30
    ジャーナル フリー
    We have synthesized a twelvefold quasicrystal Ta62Te38 by non-equilibrium solid state reactions. A transmission electron microscopy study reveals that the so-called twelvefold quasicrystal Ta62Te38 is a crystal subjected to the structure modulation. It is composed of two incommensurate layers rotated by 30° (or 90°) to each other about their normal. High resolution electron microscope images show the formation of commensurate domains and their discommensuration. The modulation is considered to be due to the rearrangement of atomic vacancies as a response to the occurrence of charge density waves.
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  • 安達 隆文, 城谷 一民, 下村 理
    41 巻 (1999) 2 号 p. 146-151
    公開日: 2010/09/30
    ジャーナル フリー
    Rare earth monophosphides REP (RE=La, Ce, Pr, Nd, Sm, Gd, Tb, Tm and Yb) crystallize in a NaCl-type structure at ambient pressure. Using synchrotron radiation X-ray diffractions of REP have been studied up to about 60 GPa at room temperature. All phosphides are found to undergo structural phase transitions at high pressures. The high pressure phases of LaP, PrP and NdP can be assigned to be a tetragonal structure, which can be seen as the distorted CsCl-type structure. The pressure-induced phase transitions of SmP, GdP, TbP, TmP and YbP occur at around 35, 40, 38, 53 and 51 GPa, respectively. The structure of the high pressure phases is unknown. X-ray diffraction patterns of the compounds with many f-elecrons become more complex at high pressure. It is expected that 4f-electrons in rare earth atoms influence the structure of the high pressure phases.
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  • 須藤 俊男
    41 巻 (1999) 2 号 p. 152
    公開日: 2010/09/30
    ジャーナル フリー
  • 高田 昌樹, 松下 信之
    41 巻 (1999) 2 号 p. 153
    公開日: 2010/09/30
    ジャーナル フリー
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