Dinuclear metal complex with phenol based dinucleating macrocyclic ligand (L
2-) derived from the [2+2] condensation of 2,6-diformyl-4-methylphenol and 1,3-diaminopropane can act as ‘complex as metal’, since axial position of the dinuclear complex is available for accepting donation from ‘another ligand’. A tetranuclear Fe(III) complex, [{Fe
2(L)(CH
3COO)}
2(μ-O)
2](PF
6)
2, was obtained by linking two {Fe
2(L)(OAc)} units with two oxo anions. In addition, a dinuclear copper (II) complex, [Cu
2(L)](ClO
4)
2, was reacted with [Cr(ox)
3]
3- and [Co(CN)
6]
3- as ‘complex as bridging ligand’, to afford [Cu
2(L)]
3[Cr(ox)
3]
2·6MeOH having a discrete octanuclear structure and [Cu
2(L)]
3[Co(CN)
6]
2·6MeOH·2DMF having 2-D grid structure, respectively.
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