In order to study the growth and constituent of aluminum-alloyed layer formed on the surface of steel, steel bars were immersed into molten aluminum and iron saturated Al-Fe and Al-Mg baths from 1023 to 1123K. In the aluminum and iron saturated Al-Fe baths, the alloyed layer was composed of Al
3Fe, Al
5Fe
2 and
α-solid solution, and the formation of Al
5Fe
2 was prevailing. The growth rate of alloyed layer was greater in the iron saturated Al-Fe bath. It followed the parabolic law. In the Al-Mg baths. the thickness of alloyed layer increased with increasing magnesium content and decreased abruptly above 75mass% Mg. The product formed on the surface of steel was Al
3Fe up to 50mass%Mg and changed in the order of Al
5Fe
2, Al
2Fe and
α-solid solution with the increase of magnesium content from 75 to 90mass%Mg. The cause of such change in product was thermodynamically explained.
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