The influences of 0.008 to 0.074 mass % B and 0.21 to 0.79 mass % P on the structure and properties of cast iron brake shoe are examined with an image analyzer and an original braking test machine. The structure of cast iron consists of hard phases, viz. , eutectic cementite and steadite, distributed in a pearlitic matrix. The addition of high density P and B increases the hard phases, which raises the frictional wear resistance against the wheel steel. The wear proceeds by a series of phenomena ; intense deformation of matrix in the surface layer, crackings through the flaky graphite, after which galling occurs. The coarse eutectic cementite crystallizes in B added cast iron, which effectively improves wear resistance. The contact surface is heated above A
1 temperature and the. steadite is partially melted or softened, which enhances the braking ability of cast iron. The addition of high concentration P therfore significantly reduces braking distance.
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