In this paper, the effect of magnetic interaction between coexisting minerals in the course of development of thermo-remanent magnetism (TRM) was examined. Various combinations of minerals in the ternary system FeO-Fe
2O
3-TiO
2 were derived by heat treating the natural ferromagnetic ilmenites. Coexisting phases produced by oxidation, reduction and phase transformations during heat treatments were found in parallel alternating structures. The main results were: (1) When both of the two phases are ferromagnetic, magnetic interaction acts negatively and the TRM of the composite system tends to be reverse TRM (RTRM). RTRM of the Haruna-type is the most typical example of this case, where the two phases are both ferromagnetic ilmenites. Intensification and artificial production of RTRM of this type were interpreted by the hypothesis of “partial exsolution” during the heat treatment at 600°C-700°C. Another type of RTRM where the two phases are titanomagnetite (Ti-Mt) and ferromagnetic ilmenite was produced by reduction. As for the case of combination of two Ti-Mts, the anomalous increase of TRM and the reversal of natural remanent magnetism, studied by other investigators, were referred to. (2) When non-ferromagnetic minerals, such as titan-hematite, rutile, non-ferromagnetic ilmenite or ulvöspinel, coexist with ferromagnetic ilmenite or Ti-Mt, the TRM and coercive force of the composite system are intensified remarkably: a linear relation
Jtr(
T0)/
Js(
T0)∝
Hc(
T0) was obtained for the composite of ferromagnetic ilmenite and titan-hematite and rutile.
As by-product of the present study, some information on the oxidation-reduction properties of ferromagnetic ilmenite was obtained: for example, oxidation was found to proceed in two distinct steps as the treatment temperature is raised.
View full abstract