The writer has examined the interrelation between the variation of N/CT and that of volatile matters (VM), along with the interrelation between the variation of N/C and that of N/C and that of H/C and O/C of various coals.As a result, he has found and observed the facts as follows:
(1) Huck et al.claim that VM and N wt %have negative correlation to a certain degree of coalification, and then they come to bear positive correlation, and that coals can be clas-sified into two series according to the amount of N contained in their original matters.They are right on the whole.but in relation to some details, their assertion must be corrected.
(2) After he has examined the interrelation between N/C and VM of many kinds of coal obtained from all over the world, the writer believes that N-content in the original matters should not be classified into two series, but the secondary coalification starts from each point of indivisible variation stage.
(3) The difference among the N-content in the original matters as indicated by Huck et al.is in reality nothing but the difference brought about as a result of the primar coalific-ation, that is, the process of peat formation.
(4) In the primary coalification, N/C increases while VM., H/C, and O/C decrease.On the contrary, N/C bears positive correlation with the other three elements in peat and lignite individually.These facts show that the primary coalification is a complex process in which.more than two reactions take place.
(5) In the case of Japanese lignite, N/C of earthy lignite in remarkably higher than that of woody lignite.
(6) In the secondary coalification, the interrelation between N/C and VM can be divided into two diffeent groups as Huck et al.assert.The boundary between these groups in nearly at one with the distinctly curving part in“H/C-O/C coal band”.
(7) The chief variation in the lower rank of these two groups in the increase of N/C resulted by the split of oxygen groups.One can also discern the effects of the split of hy-drogen or hydrocarbon, too.In the coals belonging to this rank remains the positive cor-relation among N/C and H/C and O/C that can be seen in peat and lignite individuslly and so doing, complicates the variation of N/C.The lower the rank to which a coal belongs, .the more strongly this effect of positive correlation remains.
(8) The variation discerned in the higher rank is a consistent decrease of N/C accom panied by the progress of coalification.The more distinct and remarkable the effect of H/C on it, the higher the rank to which a coal belongs.Around the curving part of the“Coal” “band”above mentioned, the correlation between N/C and HC is ambiguous.
(9) The effect t of O/C appears at the early stage, and it is already conspicuous in the rank through which OH group in coals decreases.But, it tends to become weak and am-biguous if coalification advances further and the effect of H/C becomes stronger.
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