Organometal halide solar cells have gathered wide interests from the photovoltaics research fields. This newcomer established a category as “perovskite solar cells” in the solar cell classifications, such as “Solar cell efficiency tables” or NREL chart. The power conversion efficiency over 22% was achieved within a few years from its advent. In this review article, publications about perovskite solar cells were comprehensively summarized along their “submitted date”, to record the course of the progress of perovskite solar cells. At the first stage, perovskite solar cells were established as nano-structured solar cells. The efficiency up to 15% attracted the researchers in dye-sensitized solar cells and organic thin-film solar cells. After the appearance of planar hetero-junction type solar cells, the power generation mechanism of perovskite solar cells has been argued. Rapid progress of perovskite solar cell studies reached a report of 19.3% efficiency published on August, 2014. Around that time, several issues arose, such as I-V hysteresis, chloride contents. Although there were several severe comments about these issues, the developments of perovskite solar cells progressed steadily, then efficiencies over 20% were reported. At present, the highest efficiency in published papers is 21.8% of mesoscopic perovskite solar cells. Such history is summarized in this review.
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