Lo-ex is widely used because of its superior heat resistivity and particularly its low coefficient of thermal expansion, and it is standardized in our country as well as in various foreign.
This alloy is the Al-Si-Cu-Mg-Ni quinary system. As it has a considerably large content of Si compared with Cu, Mg and Ni, it may be considered Silumin added with Cu, Mg and Ni. From this point of view, Si percentage of 11.0-13.0 established in the above mentioned standards causes the contradiction to admit different structures in the primary crystal of the alloy belonging to the same specification, because the above range of Si content spreads over both sides of the Al-Si binary eutectic point.
The author and his associates have found the hyper-eutectic structure with the casting surface similar to the tortoise shell in one case, and the hypo-eutectic with the casting surface similar to the bullfrog's skin in other case, although the tested alloy is not tried for modification treatment with Na and even is fixed at the value of the hyper-eutectic side of the Al-Si binary system in Si percentage (ex. 12.0%). Clearing the cause for the aspect of both structures has developed into establishing the method of manufacturing Lo-ex with both structures.
A comparison, in addition, has been made on Lo-ex of both structures concerning the mechanical properties, the coefficient of thermal expansion and the castabilities.
The results obtained are as follows:
1) The adding elements of Lo-ex which have been certified to effect the transition of Al-Si binary eutectic point-Cu, Mg and Ni-have naturally same effect to the structure of this alloy. But, as far as Si percentage is maintained at 12% approximately and the content of Cu, Mg and Ni is within its specified range respectively, the different structures discribed above result from Ca contained in metallic silicon.
2) Lo-ex of Ca content less than 0.0050% produces hyper-eutectic type while Lo-ex of more than that produces hypo-eutectic.
3) The Na addition well-known as modification treatment certainly produces Lo-ex of hypo-eutectic type, but the casting surface does not assume bullfrog's skin. Moreover the raw materials used in this study are the virgin ingots only, and those Na contents are too small to have capability of modification treatment.
4) Lo-ex of hyper-eutectic type is superior in tensile properties, which is attributable to the far much less microshrinkage. The other mechanical properties have not any appreciable differences.
5) Lo-ex of hyper-eutectic type has the less coefficient of thermal expansion than that of hyper-eutectic type.
6) Lo-ex of hyper-eutectic type. has larger micro-shrinkage, and it is to some extent superior in runnability.
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