The precipitation hardening and its effects on recrystallization were investigated on Al-0.3wt.%Zr alloys containing various amounts of Fe and Si. The results were summarized as follows.
(1) The rate of precipitation hardening of Al-0.3wt.%Zr alloys, solution heat-treated at a temperature as high as 640°C, was very low. The time required to reach the maximum hardness was more than 6000hr. at 250°C, about 1000hr. at 350°C, and about 400hr. at 450°C.
(2) In general, the height of peak hardness increased with the drop of ageing temperature. However, at 450°C, the alloys were scarcely hardened in precipitation.
(3) The precipitation hardening of these alloys was much accelerated by the addition of small amounts of Fe and Si. As the results, the time required to reach the peak hardness was shorter and the height of peak was also larger.
(4) In hight temperature aging, the so-called grain boundary reaction was shown in high grade alloys, but not in alloys having high contents of Fe and Si.
(5) A rod-shaped insoluble compound appeared on the grain boundary in low grade alloys. It was confirmed by scanning analysis with X-ray micro-analyzer that the compound had higher contents of Fe, Si, and Zr; but its accurate composition and crystal structure were not determined.
(6) The effects of the precipitate on the prevention of recrystallization and boundary migration were expected to be most remarkable at some optimum size of the precipitate. Smaller particles seemed to be unstable and larger ones seemed to have little effects.
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