The ageing characteritics of Mg-0.2wt.%Ce alloy which has the highest workability among the alloys of Mg-Ce system, were studied by means of hardness measurements and transmission electron microscopy.
In isochronal ageing of the alloy cold worked after solution heat treatment, softening which would be due to dislocation rearrangement occurred up to about 75°C, and then, hardening due to precipitation of Mg
9Ce gradu ally took place in the range up to about 200°C.
In isothermal ageing in a temperature range of 100200°C, an age-hardening effect was found in the alloy cold worked after solution heat treatment, but little effect was found in the alloy with no cold working after the treatment.
In the former alloy, the precipitation of coherent spherical particles preferentially occurred on dislocations and developed to plates on (1120) planes in magnesium matrix. Whereas, in the latter alloy, preferential precipitation of Mg
9Ce was observed on grain or sub-grain boundaries, but not in the matrix.
Split ageing behavior was also studied for the former alloy. The pre-ageing treatment was performed at 50 and 100°C immediately followed by the final ageing treatment at 200°C. When the ageing time at the pre-ageing was shorter, the hardness was higher at a very early stage of the final ageing. Although same softening more promptly occurred after reaching the maximum hardness, the maximum hardness value in the final ageing was lower when the pre-ageing time was longer. The hardness was nearly constant in the last stage of the final ageing, independent of pre-ageing time. However, the value for the specimens pre-aged at 100°C was somewhat lower than that for the specimens pre-aged at 50°C.
The improvement of mechanical properties of the alloy can be explained by the locking of dislocation due to the particles preferentially precipitated on the alloy.
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