Magnesium alloys are lightweight materials with high specific strength. On the other hand, magnesium alloys has excellent to casting characteristics, machineability, and electromagnetic shield characteristics etc. In recent year, magnesium products are looked for complication and precision. Adhesion is one of the essential technology for making industrial products. Adhesion technology can apply for making the electronic equipment and sporting goods. Magnesium product will be able to lightweight and recycling. Chromate is now listed as a known carcinogen and is being phased out as a conversion coating material. This paper describes bond strength of chromate conversion coating, manganese conversion coating, tin conversion coating, and Mg (OH)
2 coating as a chromate-free conversion coating on AZ31B and AZ91D magnesium alloys. The results of tensile shear strength test with epoxy resin that tensile shear strength of chromate conversion coating showed 10∼12MPa. Especially Mg (OH)
2 coating showed higher tensile shear strength (16MPa) with cure temperature at 363 K. The results of tensile shear strength test with modified silicone resin that tensile shear strength of manganese conversion coating and tin conversion coating are about equal to tensile shear strength of chromate conversion coating. Tensile shear strength of AZ31B magnesium alloy and tensile shear strength of AZ91D magnesium alloy showed similar tensile shear strength (3MPa). The results of tensile shear strength test with phenolformaldehyde resin that tensile shear strength of tin conversion coating showed higher than tensile shear strength of chromate conversion coating. Especially, tin conversion coating showed high tensile shear strength (6MPa) with cure temperature at 423 K. From the above results, it is obvious that these conversion coatings can be alternative to chromate-free conversion coating as surface treatment for Mg/Mg adhesion.
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