Effects of CH
3COOH on the corrosion behavior for aluminum alloys during accelerated corrosion tests were investigated. Based upon polarization curves, the dominant cathodic reaction for pitting corrosion of Al–Zn alloys was reduction of hydrogen ion because their pitting potentials were less noble, while that of Al–1mass%Mn alloys, whose pitting potentials were relatively noble, was reduction of dissolved O
2. While the corrosion rate for the Al–Zn alloys were also increased with the concentration of CH
3COOH, that for Al–1mass%Mn alloys were independent of the concentration of CH
3COOH. It is indicated that corrosion rate for Al–Zn alloys is related to the concentration of CH
3COOH added in the solutions. The relation between the corrosion rate and concentration of CH
3COOH was confirmed from immersion tests. The reason for increase in the corrosion rate for the Al–Zn alloys is due to that CH
3COOH acts as a hydrogen ion carrier rather than agent of lowering pH. The concentration of CH
3COOH is should be standardized but not the pH to increase the reproducibility of the corrosion tests.
View full abstract