Standard Gibbs free energy changes for decompositions of BaFe
2W(BaO·2FeO·8Fe
2O
3), BaFeX (BaO·FeO·7Fe
2O
3), SrFe
2W (SrO·2FeO·8Fe
2O
3), and SrFeX (SrO·FeO·7Fe
2O
3) compounds at lower temperatures were determined by the E. M. F. measurements of galvanic cells with solid electrolytes (CSZ and YSZ). Cell structures studied are as follows: [Cell I]; Pt, Ni-NiO/ZrO
2(+Y
2O
3)/O
2 in Air, Pt [Cell II]; Pt, Fe
3O
4-Fe
2O
3/ZrO
2(+Y
2O
3)/O
2 in Air, pt [Cell III]; Pt, BaFe
2W-BaM-Fe
2O
3/ZrO
2 (+Y
2O
3)/O
2 in Air, pt [Cell IV]; Pt, BaFe
2W-BaM-Fe
2O
3/ZrO
2(+Y
2O
3)/O
2 (pure,
PO2=101325 Pa), Pt [Cell V]; Pt, BaFeX-BaFe
2W-BaM/ZrO
2(+Y
2O
3)/O
2 (pure,
PO2=101325 Pa), Pt [Cell VI]; Pt, SrFe
2W-SrM-Fe
2O
3/ZrO
2(+CaO)/O
2 (pure,
PO2=101325 Pa), Pt [Cell VII]; Pt, SrFeX-SrFe
2W-SrM/ZrO
2(+CaO)/O
2 (pure,
PO2=101325 Pa), Pt The obtained results are summarized as follows: Reaction in the cell I ; 2Ni+O
2=2NiO
(This article is not displayable. Please see full text pdf.) Reaction in the cell II ; 4Fe
3O
4+O
2=6Fe
2O
3(This article is not displayable. Please see full text pdf.) Reaction in the cell III and IV ; 2BaFe
2W+O
2=2BaM+6Fe
2O
3(This article is not displayable. Please see full text pdf.) Reaction in the cell V ; (
y+2⁄2(
x−
y)) (BaO·Fe
xO·7Fe
2O
3) + O
2 = (2+
x⁄4(
x−
y)) (BaO·2Fe
yO·8Fe
2O
3) + (2
y+2−
x⁄4(
x−
y)) (BaO·6Fe
2O
3)
(This article is not displayable. Please see full text pdf.) Reaction in the cell VI ; 2SrFe
2W+O
2=2SrM + 6Fe
2O
3(This article is not displayable. Please see full text pdf.) Reaction in the cell VII ; (
y+2⁄2(
x−
y)) (SrO·Fe
xO·7Fe
2O
3) + O
2 = (2+
x⁄4(
x−
y)) (SrO·2Fe
yO·8Fe
2O
3) + (2
y+2−
x⁄4(
x−
y)) (SrO·6Fe
2O
3)
(This article is not displayable. Please see full text pdf.)
抄録全体を表示