The CO2 facilitated transport membranes we are developing require virtually no energy compared to conventional CO2 separation technologies and occupy a significantly smaller footprint (approximately one-tenth). In an effort to further increase the membrane area per unit volume beyond that of previously developed spiral-type modules, we explored the development of both hollow fiber modules and flat-membrane stack modules. Additionally, to reduce membrane production costs, the feasibility of adopting new substrate materials was investigated. As a result, although hollow fibers coated with a gel membrane on their outer surfaces exhibited membrane performance comparable to that of flat membranes, coating the inner surfaces proved to be technically unfeasible. Conversely, in the case of flat-membrane stack units, it was found that the flow configuration of the feed and sweep gases significantly influenced membrane performance, similar to heat exchangers. Among the tested configurations, the crossflow arrangement yielded the highest membrane performance. Furthermore, when the membrane substrate was replaced from PTFE to paper, all gas permeances decreased with increasing humidification, suggesting that the paper substrates responded differently to moisture compared to conventional PTFE substrates.
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