This paper describes the elucidation about the removal of surface oxidation layer of copper iron alloy for lead frame after heating processing using Na
2SO
4-electrolyzed oxidizing water (It abbreviates as Na
2SO
4 EO water). First, the etching characteristics of Na
2SO
4 EO water against the surface of copper iron alloy for lead frame was clarified using H
2SO
4 solution and NaCl EO water for comparative immersion experiments. The results showed that as for the etching efficiency on copper iron alloy, Na
2SO
4 EO water was superior to H
2SO
4 solution, while inferior to NaCl EO water. Also, Na
2SO
4 EO water more uniformly to the composition element of copper iron alloy by the etching compared with H
2SO
4 solution. As for the relationship between immersing time and etching speed, Na
2SO
4 EO water is same as NaCl EO water. Next, as for test pieces after heating processing, it did the surface oxidation layer removal experiment by the immersion. The results show that Na
2SO
4 EO water doesn't pollute the test pieces surface compared with NaCl EO water and it is possible to apply to the surface oxidation layer removal process.
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