Optimum alloy compositions of the Ni-Nb-Cr-Mo-P-B, Ni-Cr-Nb-P-B and Ni-Cr-Mo-P-B glassy alloys were investigated for trail production of separator of fuel cell. Eventually the Ni
60Nb
2Cr
16Mo
2P
16B
4, Ni
65Cr
10Nb
5P
16B
4 and Ni
65Cr
10Mo
5P
16B
4 glassy alloys were chosen from the viewpoint of having a wide supercooled liquid region.
Then the groove formability of the compositionally optimized alloys in a supercooled liquid state was studied by hot-pressing with the dies having precise grooves. A precise groove forming can be achieved by hot-pressing the Ni
60Nb
2Cr
16Mo
2P
16B
4 and Ni
65Cr
10Mo
5P
16B
4 glassy alloys in a supercooled liquid state at T
g + 20 K. However, it was difficult to form the precise grooves in the Ni
65Cr
10Nb
5P
16B
4 glassy alloy.
Finally, we successfully demonstrated that it is possible to form the grooves by hot-pressing using viscous flow deformation in a supercooled liquid state and to produce metallic glassy separators for proton exchange membrane fuel cells (PEMFC).
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