We have studied the local structure of manganese ion doped in gamma aluminum oxynitride phosphors (γ-AlON: Mn) using electron spin resonance (ESR) experiment. Six sharp peaks appear in ESR spectra of γ-AlON: Mn, together with five weak doublets. These structures are caused by the hyperfine interaction of 3
d electrons with the
55Mn nucleus of spin
I=5/2. The six peaks are attributed to the allowed transitions (Δ
MI=0) between hyperfine splitting states of
Ms=±1/2. The five doublets are interpreted as the forbidden transitions (Δ
MI=±1) between the hyperfine splitting states. The spectral feature of γ-AlON: Mn resembles with the ESR spectrum of Mn
2+ doped MgAl
2O
4 spinel, in which Mn
2+ ions are substituted for tetrahedral Mg
2+ sites. Since γ-AlON is also of the spinel structure, it is suggested that Mn
2+ ions occupy tetrahedral Al
3+ sites. We further chased the effect of Mg
2+ co-doping on ESR spectra of Mn
2+ ions in γ-AlON, in order to elucidate the luminescence enhancement in γ-AlON: Mn, Mg. It turned out that the Mg
2+ co-doping increases Mn
2+ ions at tetrahedral Al
3+ sites.
View full abstract