Irradiation experiments using
60Co γ-rays were undertaken on CCl
3F to examine the radiation damage of fluorocarbon, used as solvent in the recovery of
85Kr from the off-gas of fuel reprocessing plants operating on the solvent absorption. The conditions of irradiation were varied in the range of 2.3×10
41.1×10
6 rad/h in terms of dose rate and -3016°C in temperature, to assemble information on the kinds of degradation products generated, the relationship between decomposition rate and absorbed dose, and the effects on the decomposition exerted by certain factors (dose rate, temperature, impurities, wall materials). The results obtained included the following findings : (1) The degradation products of CCl
3F comprised halogen ions and thirteen kinds of fluorocarbons. (2) The rate of decomposition of CCl
3F and the yield of the individual degradation products were roughly proportional to the absorbed dose ; the energy decomposition of CCl
3F at -30°C was 0.013 mol/o /Mrad (
G=1.4) under a dose rate of 1.1×10
6 rad/h. (3) The decomposition rate of CCl
3F was inhibited by increasing dose rate, and promoted by rising irradiation temperature. (4) The yields of halogen ions and C
2Cl
4F
2, and the decomposition rate of CCl
3F increased with the addition of air. (5) No appreciable influence on the decomposition of CCl
3F was observed to be exercised by the presence of such materials as stainless steel, Cu and Al.
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