The permeation time-lag method have been used to determine the permeabilities, diffusion coefficients and solubilities of hydrogen and deuterium in type 304 stainless steel of three kinds of surface treated specimens ; with oxide film, reduced by H
2 gas and Pd coated. For the specimen with a thin oxide film the permeability increased abruptly at the temperature higher than 1, 050 K owing to reduction of the oxide film by H
2 gas introduced. The permeability and diffusion coefficient for hydrogen-reduced specimens agreed with those for Pd-coated specimens showing the data of bulk diffusion limited. The isotope effects for permeability Φ
H/Φ
D, diffusion coefficient D
H/D
D and solubility were about 1.4, 1.2 and 1.1, respectively. From these values θ(=hν/k) =1, 530±50K and θ' (=hν'/k) =2, 740±20K were obtained by the quantum effect of a harmonic approximation.
抄録全体を表示